Diacetatobis[1,3-bis(benzimidazol-2-yl)benzene]zinc(II) dihydrate
نویسندگان
چکیده
In the title complex, [Zn(CH(3)COO)(2)(C(20)H(14)N(4))(2)]·2H(2)O, the Zn(II) atom, which lies on a crystallographic twofold axis, is coordinated by two O atoms of two acetate ligands and two N atoms from two 1,3-bis-(benzimidazol-2-yl)benzene ligands in a distorted tetra-hedral geometry. The complex mol-ecules and solvent water mol-ecules are connected via O-H⋯N, O-H⋯O and N-H⋯O hydrogen bonds, forming a three-dimensional network.
منابع مشابه
Bis{μ-1,3-bis[(benzimidazol-1-yl)methyl]benzene-κ2 N 3:N 3′}bis[dichloridozinc(II)] dimethylformamide disolvate
In the title compound, [Zn(2)Cl(4)(C(22)H(18)N(4))(2)]·2C(3)H(7)NO, the 1,3-bis-[(benzimidazol-1-yl)meth-yl]benzene ligand bridges two ZnCl(2) units, forming a centrosymmetric dinuclear mol-ecule. The Zn(II) atom shows a distorted tetra-hedral coordination within a Cl(2)N(2) donor set.
متن کاملA coordination polymer of CdII with benzene-1,3-dicarboxylate and 1,4-bis[1-(2-pyridylmethyl)benzimidazol-2-yl]butane
The title Cd(II) coordination polymer, catena-poly[[{1,4-bis-[1-(2-pyridylmeth-yl)benzimidazol-2-yl]butane}cadmium(II)]-μ-benzene-1,3-dicarboxyl-ato], [Cd(C(8)H(4)O(4))(C(30)H(28)N(6))](n), was obtained by reaction of CdCO(3), benzene-1,3-dicarboxylic acid (H(2)btc) and 1,4-bis-[1-(2-pyridylmeth-yl)benzimidazol-2-yl]butane (L). The Cd(II) cation is six-coordinated by an N(2)O(4)-donor set. L ac...
متن کاملBis{μ-1,3-bis[(2-methyl-1H-benzimidazol-1-yl)methyl]benzene-κ2 N 3:N 3′}bis(diiodidocadmium)
In the title compound, [Cd(2)I(4)(C(24)H(22)N(4))(2)], the 1,3-bis-[(2-methyl-1H-benzimidazol-1-yl)meth-yl]benzene ligand bridges two CdI(2) units, forming a centrosymmetric dinuclear complex. The Cd(II) atom adopts a distorted tetra-hedral coordination geometry. In the crystal, complex mol-ecules are linked into columns parallel to [101] by π-π stacking inter-actions, with centroid-centroid di...
متن کاملcatena-Poly[[[diaquadiformatonickel(II)]-μ-1,4-bis(1H-benzimidazol-1-yl)benzene] dihydrate]
In the title one-dimensional coordination polymer, {[Ni(CHO(2))(2)(C(20)H(14)N(4))(H(2)O)(2)]·2H(2)O}(n), the Ni(II) atom lies on a crystallographic inversion centre. It is coordinated by two formate O atoms, two water O atoms and two N atoms from two 1,4-bis-(1H-benzimidazol-1-yl)benzene (bzb) ligands, resulting in a distorted trans-NiN(2)O(4) octa-hedral coordination geometry. The bzb mol-ecu...
متن کاملBis[μ-1,3-bis(1H-imidazol-1-yl)propane-κ2 N 3:N 3′]bis(dichloridozinc) dihydrate
The title hydrated complex, [Zn2Cl4(C9H12N4)2]·2H2O, is a discrete dinuclear zinc complex with 1,3-bis-(1H-imidazol-1-yl)propane as the bridging ligand. The complex mol-ecule lies about a crystallographic inversion centre. The Zn(II) atom exhibits a distorted tetra-hedral coordination geometry defined by two imidazole N atoms and two Cl atoms. O-H⋯Cl hydrogen bonding between the lattice water m...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008